Fugacity for Example Non-Ideal Gas
For a gas which obeys the equation of state
V = RT/P + b + cP
(per mole), the activity coefficient is given by
= e
(2bP + cP
2
)/2RT
(Equation 5-22, page 144, Dykstra's Physical Chemistry, A Modern Introduction)
with b > 0 and c > 0. Then
f is always less than or equal to P
f is always greater than or equal to P
f is sometimes greater than and sometimes less than P
the relation between f and P can not be determined
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Carl W. David
Department of Chemsitry
University of Connecticut
Storrs, Connecticut 06269-4060
(860)486-3217
david@uconnvm.uconn.edu